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It's not that the radioactive carbon in air or food doesn't decay, it does.

But something else is going on that keeps producing new carbon-14 — otherwise it would have all turned to nitrogen millions of years ago.

Fractionation during the geochemical transfer of carbon in nature produces variation in the equilibrium distribution of the isotopes of carbon (12C, 13C and 14C).

Conversly the inorganic carbon dissolved in the oceans is generally 0.7% enriched in 13C relative to atmospheric carbon dioxide.

(You can read up on radioactivity and isotopes here).

Carbon-14, the radioactive version of carbon, is rare — it only makes up one trillionth of all the carbon in the world.

Similarly, the transfer of gases in a vacuum system may involve fractionation error if the sample gas is not allowed to equilibrate it a volume.

Atoms of larger or smaller mass may be favoured in such a situation.

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